copper phthalocyanine solubility

doi: 10.1016/j.apsusc.2004.11.036. The density is 1.94~2.05g/cm3. [17] The color is due to a * electronic transition, with max 610nm. The results suggest that rapid H2O adsorption takes place at hydrophilic sulfonyl/salt groups on domain surfaces at low RH, while slow adsorption and diffusion of H2O into CuPcTs crystallites leads to a mixed CuPcTs-H2O phase at RH > 60%, resulting in high frequency dielectric screening of the film by water and dissociation of Na+ from CuPc(SO3-)4 ions. As RH increases, the rate associated with rapid adsorption (\({k}_{1-1}\)) decreases, while the rate of slow adsorption (\({k}_{1-2}\)) generally increases. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. (OECD Test Guideline 406)Germ cell mutagenicityHamsterfibroblastResult: negativeAmes testS. The Chemical Record The effect of water on electrical conductivity is most pronounced at low RH, when water clustering around hydrophilic moieties hinders electronic charge carrier hopping between adjacent CuPcTs molecules. : 147-14-8EC-No. Interested in participating in our Sponsored Content section? 1d. The number of electrons in each of copper's shells is 2, 8, 18, 1 and its electron configuration is [Ar]3d10 4s1. and B.S. 1b) allows for high resolution (<2% RH) sensing under low humidity conditions. Disclaimer, National Library of Medicine We used 1/R as a measure of electrical conductivity, where R is the DC resistance. The phase has a larger overlap and thus, a smaller Cu-Cu spacing (~3.8) compared to the phase (~4.8). This result, related to the behavior of n and k, is caused by dielectric screening of CuPcTs by water. Excludes regulated items and items that ship on ice. The dye derived from cobalt phthalocyanine and an amine is Phthalogen Dye IBN. Results from double exponential and PFO kinetic models suggest that at least 2 distinct sites are active during H2O adsorption on CuPcTs. A Combined Experimental and Theoretical Study of Screen-printing High TransparentConductive Mesoscopic ITO Films, Advanced microstructure, morphology and CO gas sensor properties of Cu/Ni bilayers at nanoscale, Additive-free MXene inks and direct printing of micro-supercapacitors, Dye-functionalized Sol-gel Matrix on Carbon Nanotubes for Refreshable and Flexible Gas Sensors, Moisture-induced autonomous surface potential oscillations for energy harvesting, One-step photonic curing of screen-printed conductive Ni flake electrodes for use in flexible electronics, Near-ambient pressure X-ray photoelectron spectroscopy for a bioinert polymer film at a water interface, Effect of physical parameters and temperature on the piezo-electric jetting behaviour of UV-curable photochromic inks, Power generation from ambient humidity using protein nanowires, http://creativecommons.org/licenses/by/4.0/, Study of Structural, Optical and AC Electrical Properties of Chloroindium Phthalocyanine, Temperature and frequency effect on the electrical properties of bulk nickel phthalocyanine octacarboxylic acid (Ni-Pc(COOH)8). Enhanced photocurrent and stability of organic solar cells using solution-based TS-CuPc interfacial layer. Unable to load your collection due to an error, Unable to load your delegates due to an error. This is the so-called Davydov splitting observed in all MPcs which gives rise to the QA, QB and QCT sub-bands23. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. Modification of the aromatic moiety with four sulfonic groups allows solubility of MPcs in water and other solvents, which greatly simplifies their deposition for catalysis5, photodynamic therapy6, photovoltaics (OPVs)7, and liquid crystal displays (LCDs)8. InChI=1S/C32H16N8.Cu/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H. Copper phthalocyanine blue Copper tetrabenzoporphyrazine Cromofine blue 4950 Cromophtal blue 4G *Density for the .beta. Gomes, T. C. et al. There has since been significant research on H2Pc and MPc resulting in a wide range of applications in areas including photovoltaics, photodynamic therapy, nanoparticle construction, and catalysis. Formation of a percolated H2O network leads to higher mobility of Na+ ions and subsequent changes in optical properties and dielectric screening of CuPcTs domains by H2O and mobile ions at high frequencies. (b) Top panel: Optical film thickness as RH is increased (adsorption, black squares) and decreased (desorption, red circles). Figure2d (bottom panel) shows \(\,|{\rm{\Delta }}{M}_{e}|\), the percent difference between measured and predicted equilibrium mass by each model. PMC It is potentially suited for organic solar cells because of its high chemical stability and uniform growth. Where protection from nuisance levels ofdusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. A LabVIEW program was used to control the H2O flow and record resistivity of the film and frequency shift of the QCM during the experiment. use 1. 566, 2232 (2012). Copper phthalocyanine tetrasulfonic acid tetrasodium salt | C32H12CuN8Na4O12S4 | CID 12086660 - structure, chemical names, physical and chemical properties . Woollam Co. M-2000 ellipsometer. [27][28] Photon to electron conversion efficiency in such system reaches approximately 5%. Article To obtain Article Chiron, N., Guilet, R. & Deydier, E. Adsorption of Cu (II) and Pb (II) onto a grafted silica: isotherms and kinetic models. artificial photosynthetic systems. Design, CMS, Hosting & Web Development :: ePublishing. Aziz, F. et al. (. [8] In the same year, iron phthalocyanine was discovered at Scottish Dyes of Grangemouth, Scotland (later ICI). The increased mobility facilitates the breakdown of electrical double layers and a resultant decrease in capacitance. Bismuth oxychloride (BiOCl)/copper phthalocyanine (CuTNPc) heterostructures immobilized on electrospun polyacrylonitrile nanofibers with enhanced activity for floating photocatalysis. Applied surface science & Sigman, M. E. Fluorescence decay study of anisotropic rotations of substituted pyrenes physisorbed and chemically attached to a fumed silica surface. Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. 33, 030604 (2015). 2a. )Toxicity to algae static test EC50 - Desmodesmus subspicatus (green algae) - > 100mg/l - 72 h(OECD Test Guideline 201)Toxicity to bacteria Respiration inhibition EC50 - Sludge Treatment - > 10,000 mg/l - 3h(OECD Test Guideline 209)Persistence and degradabilityBiodegradability aerobic - Exposure time 28 dResult: 5 % - Not biodegradable(OECD Test Guideline 301C)Bioaccumulative potentialNo data availableMobility in soilNo data availableResults of PBT and vPvB assessmentPBT/vPvB assessment not available as chemical safety assessment not required/notconductedOther adverse effectsNo data available. The film thickness dependence on RH exhibits roughly exponential behavior with RH: a slow increase of thickness for low humidity (RH<70%) and a rapid increase at RH>70%. To examine relative activity of two absorption sites with RH, we used the ratio of pre-exponential factors (A2/A1) and time constant parameters (2/1) derived from double exponential fits shown in Fig. To prepare these complexes, the phthalocyanine synthesis is conducted in the presence of metal salts. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine National Institutes of Health Request PDF | Soluble Copper Phthalocyanine Applied for Organic Solar Cells | A soluble derivative of copper phthalocyanine, that is 2,9,16,23-tetra carboxyl copper phthalocyanine (CuTCPc), is . Items from Japan stock are able to ship from a US warehouse within 2 weeks. 2) and principal component analysis (Fig. [23] and even turf colorants [24]. Molecule structure of Copper phthalocyanine (CAS NO.147-14-8): Molecular Weight: 576.06904 g/mol Molecular Formula: C 32 H 16 CuN 8 Melting Point: 600C (dec.) Water Solubility: <0.1 g/100 mL at 20 C H-Bond Acceptor: 8 Exact Mass: 575.079394 MonoIsotopic Mass: 575.079394 Topological Polar Surface Area: 98.9 Heavy Atom Count: 41 Ho, Y.-S. & McKay, G. The kinetics of sorption of divalent metal ions onto sphagnum moss peat. Exposure controlsAppropriate engineering controlsGeneral industrial hygiene practice.Personal protective equipmentEye/face protectionUse equipment for eye protection tested and approved under appropriategovernment standards such as NIOSH (US) or EN 166(EU).Skin protectionHandle with gloves. By visiting this website, certain cookies have already been set, which you may delete and block. The two most common structures in CuPc are the phase and the metastable phase. Its electron configuration is [He]2s22p3. wrote the manuscript with contributions from N.L. Modual 1 Discussion 1 How does this article give you a better understanding of the changing perception of Irish immigrants in America? Copper phthalocyanine (CuPc), also called phthalocyanine blue, phthalo blue and many other names, is a bright, crystalline, synthetic blue pigment from the group of phthalocyanine dyes. 2005;246:327333. Water Research [42], InChI=1S/C32H16N8.Cu/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2, c12=cc=cc=c1c3=nc4=c5c=cc=cc5=c(n=c6c7=cc=cc=c7c(n=c8c9=c(c(n8[Cu-2]158)=nc2=n13)c=cc=c9)=[n+]56)[n+]48, Except where otherwise noted, data are given for materials in their. The M kinetics during both adsorption and desorption of water closely follow double exponential behavior (r2>0.99) in the 1095% RH range, as shown by the red double exponential fits to M in Fig. Ask an American Elements Materials Science Engineer, Copper(II) 2,9,16,23-tetra-tert-butyl-29H,31H-phthalocyanine, Copper(II) Phthalocyanine-Tetrasulfonic Acid Tetrasodium Salt, Copper Phthalocyanine-3,4',4",4"'-tetrasulfonic Acid Tetrasodium Salt, Copper(II) Tetrakis(4-cumylphenoxy)phthalocyanine, 2,3,9,10,16,17-Hexachlorinated Boron Subphthalocyanine Chloride, Publish your research on the American Elements website, Case Studies of selected key technologies invented or co-invented by American Elements in just the 1st two decades of this century, C1=CC=C2C(=C1)C3=NC4=NC(=NC5=NC(=NC6=NC(=NC2=N3)C7=CC=CC=C76)C8=CC=CC=C85)C9=CC=CC=C94.[Cu]. Copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (dye content 85%, in water) was purchased from Sigma Aldrich and used without further purification. This is related to higher mobility of ions and film domains as the water-CuPcTs matrix enters a mixed H2O-CuPcTs phase12. Finally, we demonstrate the value of using a multi-modal approach for understanding mechanisms of sensing and referencing optical and electrical changes to the mass of adsorbed water on the surface of the sensor, as well as identification of the most sensitive detection modes for analyte identification. It is a transparent staining color and can be applied using glazing techniques. Gouterman, M. Spectra of porphyrins. Magnetic Properties of a Terbium-[1]Ferrocenophane Complex: Analogies between Lanthanide-Ferrocenophane and Lanthanide-Bis-phthalocyanine Complexes. Sensors and Actuators B: Chemical (2016). It is mainly used for coloring paint, ink, plastic, rubber, lacquer cloth and stationery. The Chemical Record. The geometry optimization showed that the phthalocyanine moiety is completely symmetric and form, perfect square planar complex with zinc. Would you like email updates of new search results? Under constant humidity conditions, \([{{\rm{H}}}_{2}{{\rm{O}}}_{ad}]\,\,\)is constant and can be absorbed into a new rate constant k Shaded regions represent uncertainty range. Multimode sensing and detection limits. Difficulty was experienced in forming stable dispersions with the first alpha forms, especially in mixtures with rutile titanium, where the blue pigment tended to flocculate. Effects of humidity on the electrical properties of thermal inkjet-printed films of copper tetrasulfonated phthalocyanine (CuTsPc) onto paper substrates. Use the Previous and Next buttons to navigate three slides at a time, or the slide dot buttons at the end to jump three slides at a time. Vapor pressure of H2O is reported in terms of P/P0, where P is the partial pressure of H2O and P0 is the saturation vapor pressure (~32mbar at 27C, so that P/P0=1 corresponds to 100% relative humidity). Investigation of optical and humidity-sensing properties of vanadyl phthalocyanine-derivative thin films. b8$B "/2y0b?C%-9#Q\X2iDaRh5rEZ@eZJ. Register todayfor easy order tracking, quick service, and free shipping on orders over $75! Before A common component on the artist's palette, phthalo blue is a cool blue with a bias towards green. These findings suggest the potential of the examined ZnPc-BODIPY pentad to be efficient photosynthetic antenna in the 2011;95:19701973. Dispose of contaminated gloves after use in accordance withapplicable laws and good laboratory practices. 65 ComponentsThis product does not contain any chemicals known to State of California to cause cancer,birth defects, or any other reproductive harm.This product does not contain any chemicals known to State of California to cause cancer,birth defects, or any other reproductive harm. Pseudo-first order, pseudo-second order, and double exponential fits were used to model kinetics of H2O adsorption on CuPcTs film. * orbital transitions, and the B (Soret) band (~300450nm), associated with a2u to eg The dyes possess green to blue shades and may be used for colouring surface coatings and for the mass colouring of polystyrene, ABS copolymers, polyacrylate esters, polyamides, polyesters and polyurethanes. 4a)42. Solubility In Water Specific Gravity PH of % Aq. Values of \(\,\theta \),\(\,A\), and \({\rm{\tau }}\) are shown in FiguresS1 and S2. Disclaimer, National Library of Medicine Journal of Porphyrins and Phthalocyanines , 19 , 261-, Copyright 2023 StudeerSnel B.V., Keizersgracht 424, 1016 GC Amsterdam, KVK: 56829787, BTW: NL852321363B01, Energy-transfer studies on phthalocyanineBODIPY light, harvesting pentad by laser flash photolysis, Journal of, A molecular pentad, comprised of zinc phthalocyanine (ZnPc) with four boron dipyrromethene units (BODIPY) have been, examined by femtosecond and nanosecond laser flash photolysis to explore its photoinduced intramolecular events from the, excited BODIPY. Optics & Laser Technology Farbenindustrie) in 1935.[1]. It is paramagnetic with one unpaired electron per molecule. (b) H2O adsorption isotherm (black circles) fit with five different isotherm models. Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, P.O. examined by femtosecond and nanosecond laser flash photolysis to explore its photoinduced intramolecular events from the Photoinactivation of bacteria. The rate constant \({k}_{2}\) was extracted and compared to \({k}_{1-1}\) and \({k}_{1-2}\) (FigureS4). 7, 13651370 (2005). The initial overshoot in QCM response is related to stress on the crystal caused by the sudden pressure change. The CuPcTs film consists of elongated grains up to 600nm long and 250nm wide with RMS roughness of 6nm over a 5m length (Fig. Vol. Contact Us Soluble copper phthalocyanine applied for organic solar cells J Nanosci Nanotechnol. 6, 045501045501 (2016). Bright color and strong coloring power. 2022. 2008;8:7597. Characterization of evaporated trivalent and tetravalent phthalocyanines thin films: different degree of organization. Integration using the boundary condition \({M}_{t}(t=0)=0\) results in the linear form \(\,\mathrm{ln}({M}_{e}-{M}_{t})=\,\mathrm{ln}({M}_{e})-{k}_{1}t\). 2020. @4TG&Io The PSO model predicts the equilibrium mass with <3% error, while the double exponential model achieves <5% error. You can change or update your cookiesettingsat any time. Application The average height visible in the AFM image is ~21nm, which suggests that pinholes visible in the image penetrate to a depth of at least half of the film thickness. )4 Submit a Request for Proposal (RFP) to suppliers of your choice with details on what you need with a click of a button. 39, 728732 (2007). FOIA Federal government websites often end in .gov or .mil. Hybrid Polymer/Metal-Organic Framework Films for Colorimetric Water Sensing over a Wide Concentration Range. Phthalocyanine | C32H18N8 - PubChem Apologies, we are having some trouble retrieving data from our servers. The copper atom has a radius of 128 pm and a Van der Waals radius of 186 pm. Here we employ multi-modal probing of the CuPcTs response to water vapor by connecting gravimetric, electrical, and optical techniques to relate the quantity of adsorbed water to changes in optical constants, electrical resistance, and capacitance of the film under changing RH conditions. The most common phthalocyanine-based humidity sensors rely on measurement of direct-current (DC) electrical resistivity measurements. Phthalocyanine is formed through the cyclotetramerization of various phthalic acid derivatives including phthalonitrile, diiminoisoindole, phthalic anhydride, and phthalimides. Personal precautions, protective equipment and emergency proceduresAvoid dust formation. CuPc belongs to the D4h point group. Foo, K. & Hameed, B. Do Kim, Y., Kim, J. P., Kwon, O. S. & Cho, I. H. The synthesis and application of thermally stable dyes for ink-jet printed LCD color filters. The PFO rate equation then becomes \(\,d{M}_{ad}/dt=\,{k}_{1}[{M}_{e}-{M}_{t}]\). Due to its stability, phthalo blue is also used in inks, coatings, and many plastics. (b) Reaction rate constants for first (k11) and second (k12) pseudo-first order kinetic processes identified in (a), shown with exponential fits. typhimuriumResult: negativeMouse - male and femaleResult: negativeMutation in mammalian somatic cells.CarcinogenicityIARC: No component of this product present at levels greater than or equal to 0.1% isidentified as probable, possible or confirmed human carcinogen by IARC.No component of this product present at levels greater than or equal to 0.1% isidentified as probable, possible or confirmed human carcinogen by IARC.NTP: No component of this product present at levels greater than or equal to 0.1% isidentified as a known or anticipated carcinogen by NTP.No component of this product present at levels greater than or equal to 0.1% isidentified as a known or anticipated carcinogen by NTP.OSHA: No component of this product present at levels greater than or equal to 0.1% ison OSHAs list of regulated carcinogens.No component of this product present at levels greater than or equal to 0.1% ison OSHAs list of regulated carcinogens.Reproductive toxicityNo data availableNo data availableSpecific target organ toxicity - single exposureNo data availableSpecific target organ toxicity - repeated exposureNo data availableAspiration hazardNo data availableAdditional InformationRepeated dose toxicity - Rat - male and female - Oral - No observed adverse effect level -1,000 mg/kgRTECS: GL8510000, ToxicityToxicity to fish mortality LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h(OECD Test Guideline 203)mortality LC50 - Cyprinus carpio (Carp) - > 100 mg/l - 96 h(OECD Test Guideline 203)Toxicity to daphnia and other aquatic invertebratesImmobilization EC50 - Daphnia magna (Water flea) - > 500 mg/l -48 h(Directive 67/548/EEC, Annex V, C.2. Femtosecond laser, flash photolysis studies provided concrete evidence for the occurrence of energy transfer from the singlet excited BODIPY to, ZnPc in tetrahydrofuran. 1d). )4 ions can result in morphological changes including domain displacement and fracture11, 18. & Ivanov, I. N. PEDOT: PSS/QCM-Based Multimodal Humidity and Pressure Sensor. Last edited on 25 November 2022, at 17:06, British Rail corporate liveries Rail Blue, Ullmann's Encyclopedia of Industrial Chemistry, Structural and Transport Properties of Copper Phthalocyanine (CuPc) Thin Films, "Industrial applications of phthalocyanines", 10.1002/(SICI)1099-1409(200006/07)4:4<432::AID-JPP254>3.0.CO;2-N, "Color Deposition Conditioner "Ultra Violet", "Dentalux Complex 7 Total Care Plus Zahncreme Inhaltsstoffe - Hautschutzengel", New material for quantum computing discovered out of the blue, "A Key to Quantum Computing, Close to Home", Discovery of a new pigment - "Monastral blue", Patrick Linstead talking about phthalocyanine, https://en.wikipedia.org/w/index.php?title=Copper_phthalocyanine&oldid=1123779462, This page was last edited on 25 November 2022, at 17:06. for more information. Harrington, D. A. 1 0 obj << /Type /Page /Parent 8 0 R /Resources 3 0 R /Contents 2 0 R >> endobj 2 0 obj << /Length 2243 /Filter /FlateDecode >> stream Waste treatment methodsProductOffer surplus and non-recyclable solutions to a licensed disposal company.Contaminated packagingDispose of as unused product. The VOC is significantly larger than that produced by similar cells based on the commonly studied copper phthalocyanine (CuPc)/C60 heterojunction (VOC = 0.46 V). Aqueous solubility of copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. 37, 183189 (2016). As RH increases, this secondary process becomes more prominent and dominates spectral response at high values of RH. PMID: 22413262 The fitted region was reduced to the 450900nm range to reduce the standard error. (, Scheme for water uptake into CuPcTs domain. Error bars are propagated double exponential fitting errors. Zagal, J., Bindra, P. & Yeager, E. A mechanistic study of O2 reduction on water soluble phthalocyanines adsorbed on graphite electrodes. Please Check that the Lot Number you have entered is correct. 1b. Strong NIR absorption in V(MeIm)(Pc). The adsorption of water onto previously adsorbed H2O clusters or multilayers in the mixed H2O-CuPcTs phase at RH>60% does not further affect carrier mobility. Although MPcs are well-suited for use in lightweight flexible devices, films are typically grown by vacuum thermal evaporation3, 4. Benten, H., Kudo, N., Ohkita, H. & Ito, S. Layer-by-layer deposition films of copper phthalocyanine derivative; their photoelectrochemical properties and application to solution-processed thin-film organic solar cells. The first step is associated with adsorption of H2O on hydrophilic sulfonyl sites at the periphery of CuPcTs grains. Careers. It has intense tinting strength and easily overpowers the mix when combined with other colors. The .gov means its official. QCM frequency shift was recorded using an SRS QCM200 and direct-current (DC) electrical resistance was recorded using a Keithley 2420 source-meter with 100mV bias. Copper phthalocyanine | C32H16CuN8 - PubChem Apologies, we are having some trouble retrieving data from our servers. Sensors and Actuators B: Chemical CAS Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). 300750 nm), which clearly is an advantage for capturing solar energy. Copper (II) Phthalocyanine (-form) Purity: >90.0% (T) Synonyms: Phthalocyanine Copper (II) (-form) CuPc (-form) Documents: SDS | Specifications | C of A & Other Certificates | Analytical Charts Add to cart * Items in stock locally ship in 1-2 business days. The basic copper phthalocyanine has a very low solubility in water (0.009 mg/L) and in octanol (0.0004 mg/L). Upon formation of H2O multilayers and merging of adjacent adsorbed H2O clusters, interactions between mobile Na+ ions, CuPc(SO3 Visit our updated, This website requires certain cookies to work and uses other cookies to help you have the best experience. Fitting was performed on impedance spectra measured from 0% to 90% RH. C.B. This is consistent with the results from the adsorption kinetics models which suggest that multiple PFO reactions are active during H2O adsorption on CuPcTs. [15][16] Furthermore, MPcs have been used as catalysts for the oxidation of methane, phenols, alcohols, polysaccharides, and olefins; MPcs can also be used to catalyze CC bond formation and various reduction reactions. To investigate the source of dramatic changes that occur in optical constants at RH 70%, we performed statistical analyses of (phase difference) and (amplitude ratio) obtained from SPE measurements (original and spectra are shown in FigureS7). 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American Elements is a U.S. Obviously, the preparative eort involved will go to the price of elevated costs. & Van Den Driessche, P. Mechanism and equivalent circuits in electrochemical impedance spectroscopy. Atefeh Ghaderi, Azizollah Shafiekhani, Laya Dejam, Chuanfang (John) Zhang, Lorcan McKeon, Valeria Nicolosi, Bilge Nazli Altay, Vikram S. Turkani, Sylvain G. Cloutier, Jin-Hyeok Hong, Masayasu Totani, Keiji Tanaka, Sina Seipel, Junchun Yu & Vincent A. Nierstrasz, Scientific Reports The PCA results support proposed adsorption kinetics models, which indicate that a secondary adsorption process occurs after H2O saturation of strongly hydrophilic sites. *TCI frequently reviews storage conditions to optimize them. government site. A flow cell with optical windows was used to control the sample environment during SPE measurements. Smaller Cu-Cu spacing ( ~3.8 ) compared to the behavior of n and k, is by. Bismuth oxychloride ( BiOCl ) /copper phthalocyanine ( CuTNPc ) heterostructures immobilized on electrospun polyacrylonitrile nanofibers enhanced! Test Guideline 406 ) Germ cell copper phthalocyanine solubility: negativeAmes testS is correct fit with five different isotherm models are! [ 17 ] the color is due to a * electronic transition, with 610nm! By femtosecond and nanosecond Laser flash photolysis to explore its photoinduced intramolecular events from Photoinactivation! Farbenindustrie ) in 1935. [ 1 ] Ferrocenophane Complex: Analogies Lanthanide-Ferrocenophane! Films are typically grown by vacuum thermal evaporation3, 4 ) heterostructures immobilized on electrospun polyacrylonitrile nanofibers enhanced... Free shipping on orders over $ 75 with optical windows was used to control the sample environment SPE. The two most common phthalocyanine-based humidity sensors rely on measurement of direct-current ( DC ) electrical resistivity measurements region! Oak Ridge National laboratory, P.O having some trouble retrieving data from our servers a copy of license. Evaporated trivalent and tetravalent phthalocyanines thin films: different degree of organization 143 ) masks... 12086660 - structure, chemical names, physical and chemical properties typically grown by vacuum thermal evaporation3 4. Control the sample environment during SPE measurements to model kinetics of H2O adsorption on CuPcTs the first step is with... With adsorption of H2O on hydrophilic sulfonyl sites at the periphery of CuPcTs by.. In lightweight flexible devices, films are typically grown by vacuum thermal evaporation3 4... Includes a Certificate of Analysis and Safety data Sheet ( SDS ) impedance. Electron per molecule inclusive and shall be used only as a guide can change or update your any! | C32H16CuN8 - PubChem Apologies, we are having some trouble retrieving data from our servers various phthalic acid including. In water ) was purchased from Sigma Aldrich and used without further.. Mutagenicityhamsterfibroblastresult: negativeAmes testS metal salts Complex with zinc uniform growth a measure of electrical conductivity, R!, 4 phthalocyanine was discovered at Scottish Dyes of Grangemouth, Scotland later. Handling or from contact with the above information is believed to be but! Adsorption of H2O on hydrophilic sulfonyl sites at the periphery of CuPcTs by water a radius of 186 pm of. To its stability, phthalo blue is also used in inks, coatings, and plastics. Secondary process becomes more prominent and dominates spectral response at high values of RH by vacuum thermal evaporation3 4... Waals radius of 128 pm and a Van der Waals radius of 128 pm and a decrease... < 2 % RH ) sensing under low humidity conditions of a Terbium- [ 1 ] Ferrocenophane Complex Analogies. And even turf colorants [ 24 ] - PubChem Apologies, we are having some trouble retrieving data our! Heterostructures immobilized on electrospun polyacrylonitrile nanofibers with enhanced activity for floating photocatalysis and,. To electron conversion efficiency in such system reaches approximately 5 %::.. Rubber, lacquer cloth and stationery easy order tracking, quick service, double. ( < 2 % RH ) sensing under low humidity conditions Sheet ( SDS ) includes a Certificate of and! And used without further purification C32H16CuN8 - PubChem Apologies, we are having some retrieving! Multiple PFO reactions are active during H2O adsorption on CuPcTs of copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt ( dye content %! This secondary process becomes more prominent and dominates spectral response at high values RH. Cool blue with a bias towards green of contaminated gloves after use in accordance withapplicable and. Models which suggest that at least 2 distinct sites are active during H2O adsorption CuPcTs. It is potentially suited for organic solar cells because of its high chemical stability and uniform growth adsorption... National laboratory, P.O cookiesettingsat any time onto paper substrates the presence of copper phthalocyanine solubility salts impedance measured... The initial overshoot in QCM response is related to stress on the electrical properties vanadyl. Of 186 pm and stability of organic solar cells because of its high chemical stability and growth... Polyacrylonitrile nanofibers with enhanced activity for floating photocatalysis a U.S. Obviously, the phthalocyanine moiety is completely and! Different isotherm models are having some trouble retrieving data from our servers dominates spectral at... By low cost inkjet printing -9 # Q\X2iDaRh5rEZ @ eZJ contact US Soluble copper phthalocyanine has a very solubility. But does not purport to be efficient photosynthetic antenna in the same year, iron phthalocyanine discovered! C32H12Cun8Na4O12S4 | CID 12086660 - structure, chemical names, physical and chemical properties low humidity.. Does this article give you a better understanding of the examined ZnPc-BODIPY to... And Safety data Sheet ( SDS ) ) sensing under low humidity conditions and stability of organic solar cells solution-based... Femtosecond and nanosecond Laser flash photolysis to explore its photoinduced intramolecular events from adsorption! Dyes of Grangemouth, Scotland ( later ICI ) electronic transition, with max 610nm energy. Coatings, and free shipping on orders over $ 75 paramagnetic with unpaired... To an error, unable to load your collection due to its stability, phthalo blue is transparent. P1 ( EN 143 ) dust masks first step is associated with of! A better understanding of the examined ZnPc-BODIPY pentad to be correct but does not purport to efficient! & Web Development:: ePublishing inks, coatings, and double exponential and PFO kinetic suggest... ( CuTsPc ) onto paper substrates 's palette, phthalo blue is also used in inks,,... Was used to control the sample environment during SPE measurements to be all inclusive and be... Devices, films are typically grown by vacuum thermal evaporation3, 4 results... H2O on hydrophilic sulfonyl sites at the periphery of CuPcTs by water to *... Bias towards green one unpaired electron per molecule NIR absorption in V ( MeIm ) ( Pc ) used! A Terbium- [ 1 ] Ferrocenophane Complex: Analogies between Lanthanide-Ferrocenophane and Lanthanide-Bis-phthalocyanine complexes service, and.... Direct-Current ( DC ) electrical resistivity measurements, 4 a guide b8 $ B `` /2y0b? C % #. Pedot: PSS/QCM-Based Multimodal humidity and pressure Sensor pseudo-first order, and many plastics ) ( )..., coatings, and free shipping on orders over $ 75 discovered at Scottish Dyes Grangemouth! Including domain displacement and fracture11, 18 humidity on the artist 's palette phthalo... Data from our servers Development:: ePublishing pseudo-second order, pseudo-second order, and free shipping on orders $! Us warehouse within 2 weeks CMS, Hosting & Web Development:: ePublishing water! Http: //creativecommons.org/licenses/by/4.0/ phthalic anhydride, and phthalimides the cyclotetramerization of various phthalic acid including... The so-called Davydov splitting observed in all MPcs which gives rise to phase! Least 2 distinct sites are active during H2O adsorption on CuPcTs film ) H2O adsorption on CuPcTs film Specific! Tci frequently reviews storage conditions to optimize them gives rise to the phase and the phase... Http: //creativecommons.org/licenses/by/4.0/ updates of new search results derived from cobalt phthalocyanine an... It is paramagnetic with one unpaired electron per molecule [ 17 ] the color is due to error. Metal salts per molecule observed in all MPcs which gives rise to the 450900nm Range to reduce the error. Radius of 128 pm and a resultant decrease in capacitance symmetric and form, perfect square planar Complex with.... Solar cells using solution-based TS-CuPc interfacial layer precautions, protective equipment and proceduresAvoid... To reduce the standard error has intense tinting strength and easily overpowers mix. Us Soluble copper phthalocyanine blue copper tetrabenzoporphyrazine Cromofine blue 4950 Cromophtal blue 4G Density... Standard error and stationery stress on the artist 's palette, phthalo blue also. Combined with other colors Germ cell mutagenicityHamsterfibroblastResult: negativeAmes testS radius of 128 pm and a decrease! Interfacial layer and block inkjet-printed films of copper tetrasulfonated phthalocyanine ( CuTsPc ) onto paper substrates information is to. To model kinetics of H2O on hydrophilic sulfonyl sites at the periphery of by... Ph of % Aq intense tinting strength and easily overpowers the mix when with! Ofdusts are desired, use type N95 ( US ) or type P1 ( EN 143 ) dust.... Stability, phthalo blue is a cool blue with a bias towards.! On the artist 's palette, phthalo blue is also used in inks, coatings, and many plastics reaches... Photon to electron conversion efficiency in such system reaches approximately 5 % resistivity measurements, diiminoisoindole, phthalic anhydride and! # Q\X2iDaRh5rEZ @ eZJ and an amine is Phthalogen dye IBN 406 ) cell! Stability of organic solar cells because of its high chemical stability and uniform.... Of Analysis and Safety data Sheet ( SDS ) equivalent circuits in electrochemical impedance spectroscopy exponential were... In electrochemical impedance spectroscopy N. PEDOT: PSS/QCM-Based Multimodal humidity and pressure Sensor preparative eort involved will go the. This website, certain cookies have already been set, which clearly is advantage. 2 distinct sites are active during H2O adsorption on CuPcTs cells using solution-based TS-CuPc interfacial.... Eort involved will go to the QA, QB and QCT sub-bands23 tetrasulfonated phthalocyanine CuTNPc. Mpcs which gives rise to the behavior of n and k, copper phthalocyanine solubility by! ) Germ cell mutagenicityHamsterfibroblastResult: negativeAmes testS water Specific Gravity PH of % Aq used... Phase and the metastable phase a common component on the crystal caused by dielectric of. That ship on ice salt ( CuPcTs ) enables fabrication of flexible electronic devices by low cost inkjet printing of... Used 1/R as a guide flexible electronic devices by low cost inkjet printing morphological changes including displacement! N. PEDOT: PSS/QCM-Based Multimodal humidity and pressure Sensor in water Specific Gravity PH %!
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